Resumen

BRAVO, José. THE ORGANIC CHEMISTRY NOTEBOOK SERIES, A DIDACTICAL APPROACH,^® (I) A THEORETICAL MECHANISTIC APPROACH TO DIASTEROSELECTIVE SYNTHESIS OF CIS-1,2-DIALKENYLCYCLOPROPANOLS AND SUBSEQUENT OXY-COPE REARRANGEMENT BY JIN KUN CHA ET AL.. Rev. Bol. Quim [online]. 2005, vol.22, n.1, pp.1-10. ISSN 0250-5460.

The Organic Chemistry Notebook Series, A Didactical Approach,^® has a reviewing character and it is intended to meet the needs of students debuting in studies of synthesis, in order to increase their capabilities to understand in an explicit manner, synthesis works already published. This discussion analyzes the article published by Prof. Jin Kun Cha (former Professor at the University of Alabama at Tuscaloosa, currently Professor at Wayne University, Detroit) entitled: Diasteroselective Synthesis of cis-1,2-Dialkenylcyclopropanols and Subsequent Oxy-Cope Rearrangement.

Palabras clave : Kulinkovich hydroxycyclopropanation; cis-1,2-dialkenylcyclopropanols; oxy-Cope rearrangement; hydroazulenic sesquiterpenes; theoretical reaction mechanism.